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Step 1 of 5
Heat the joint, not the solder
This is the one thing that separates a good joint from a bad one. Touch the iron to the pad and the pin together for a second or so, then feed solder into the joint itself, not onto the iron tip. The heated metal melts the solder and pulls it in. If you melt solder on the tip and drop it on, you get a grey blob sitting on top that looks connected and is not.
Pro Tip
A good joint is shiny and shaped like a tiny volcano. Dull, cracked or ball-shaped means reheat it and add a little fresh solder.